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Ultrafast broadband sensitive magneto-chiroptical microscopy to track the consequences of symmetry breaking in solution-processable semiconductors

Objective

Chiral solution-processable semiconductors are a new class of materials that could revolutionize optoelectronics by enabling circularly polarized light (CPL) emission and spin control without external magnetic fields at room temperature. This could enhance the efficiency of displays, solar cells, holography, cryptography, and biomedical imaging, while opening new possibilities in quantum information processing. However, current trial-and-error approaches, limited by the absence of suitable techniques to probe mechanisms, prevent systematic breakthroughs in designing chiral materials with strong CPL emission and spin polarization.

MACHIRO will overcome these limitations. We will develop the first ultrafast broadband magneto-chiroptical microscope to map the Stokes vector of light polarization emitted from chiral materials with diffraction-limited spatial and femtosecond-temporal resolution. This will enable us to directly track the interplay between charge, spin, and light polarization in time and space, to mechanistically understand how CPL and spin polarization arise from structural chirality imprint on the excited state.

We will use this new tool to study a range of i) heavy-element containing chiral halide perovskite semiconductors, as well as ii) purely molecular twisted materials with much less spin orbit coupling. We will systematically vary dimensionality (3D bulk to 0D quantum dots), hierarchical level of chirality, helical pitch and addition magnetic impurities, while always monitoring the role of local disorder through mapping. Thus, we will identify dominant loss channels and arrive at a unified mechanism of how light and spin polarization are connected.

Finally, we will integrate insights across all materials, establishing universal design rules for using chirality to control spin and light simultaneously, enabling next-generation solution-processable spin-optoelectronic technologies with unprecedented energy efficiency.

Keywords

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Topic(s)

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HORIZON-ERC - HORIZON ERC Grants

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Call for proposal

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(opens in new window) ERC-2025-STG

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Host institution

ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 2 173 004,00
Address
BATIMENT CE 3316 STATION 1
1015 LAUSANNE
Switzerland

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Region
Schweiz/Suisse/Svizzera Région lémanique Vaud
Activity type
Higher or Secondary Education Establishments
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

€ 2 173 060,00

Beneficiaries (1)

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