Development and Application of New NMR Methods for Studying Interphases and Interfaces in Batteries

Projektinformationen

BATNMR

ID Finanzhilfevereinbarung: 835073

DOI

10.3030/835073

Projekt abgeschlossen

EK-Unterschriftsdatum 11 Juni 2019

Startdatum 1 Oktober 2019

Enddatum 30 September 2025

Finanziert unter

• EXCELLENT SCIENCE - European Research Council (ERC)

Gesamtkosten

€ 3 498 219,00

EU-Beitrag

€ 3 498 219,00

Koordiniert durch

THE CHANCELLOR MASTERS AND SCHOLARS OF THE UNIVERSITY OF CAMBRIDGE
United Kingdom

Periodic Reporting for period 4 - BATNMR (Development and Application of New NMR Methods for Studying Interphases and Interfaces in Batteries)

Berichtszeitraum: 2024-04-01 bis 2025-09-30

Zusammenfassung vom Kontext und den Gesamtzielen des Projekts

The use of lithium metal as a negative electrode in a lithium-ion rechargeable battery can increase its energy density, but so far, its use is limited due to uncontrolled and inhomogeneous electrodeposition on cycling the battery due to rapid battery fade and safety issues. To solve the Li metal problem and prevent battery degradation in batteries more generally, we must understand both how the electrolyte – the liquid that transports the ions in a battery from the anode to cathode and vice versa – and the passivation layers that protect both the anode and cathode function and fail. Clearly this work is important because the development of better batteries underpin European and Global goals to reduce CO2 emissions. We must develop more sustainable batteries that last longer before failing and have higher energy densities (i.e. can run longer on a single charge).

An important tool to improve battery technology is nuclear magnetic resonance (NMR) spectroscopy because it allows chemical species to be identified. We have been pushing the use of operando methods to do this so as to understand how the different components of the battery operate synergistically. A challenge however with this method is its low sensitivity. This means it is difficult to pick up minor components – be in the molecules formed during degradation or at the interfaces in and between the various layers that make up the battery. We have thus been developing new methods to enhance the NMR signals and have applied them to look at battery reactions and Li metal dendrite formation. The overall objectives are to develop new NMR metrologies specifically designed to target key reactions or species in batteries and then to apply them to understand function and provide insight into how improve battery performance.

Arbeit, die ab Beginn des Projekts bis zum Ende des durch den Bericht erfassten Berichtszeitraums geleistet wurde, und die wichtigsten bis dahin erzielten Ergebnisse

Our work has centered on the development of Overhauser Dynamic Nuclear Polarization (DNP) methods for lithium-ion batteries. This approach as allowed us to enhance the Li metal by as much as a factor of 8 in our original experiment, and more recently by more than 100 fold, in the new facility funded as part of the ERC grant. We have worked on the theory that underpins this experiment and have applied it to understand how Li dendrites grow in the batteries. We have also performed detailed studies of how the battery electrolytes degrade and how the reactions at the cathode differ from those at the anode, and how they “talk to each other” via cross-over reactions where one species formed at one electrode migrates and reacts at the other. We have used new NMR methods to quantify how the ions move through the layers that protect the Li metal from further reaction with the electrolyte, which ultimately will help us design methods to use Li metal in batteries. We have performed studies of anode materials that are suitable for fast charging of batteries. With my colleague in the Cavendish in Cambridge (Prof. Akshay Rao), we have developed new optical approaches to “look” at battery materials charging in real time to follow the Li-ions as they move in and out of the battery electrode materials. Dissemination has been performed via speaking at multiple battery conferences. For example, I gave a talk to the Falling Walls Conference in Berlin in November 2021 "Breaking the Walls on Fast Charging", https://www.youtube.com/watch?v=0pBKV1LGoRo also giving a more detailed science presentation and contributing to a round table discussion. As part of my Koerber Award, in 2021, I discussed the role of batteries in mitigating climate change (https://www.koerber-stiftung.de/en/koerber-european-science-prize/previous-prizewinners/2021). I will also give invited talks and plenary lectures in a series of batteries conference in person in 2022-2025. I am active within the UK political arena: I was the special advisor for the House of Lord’s Science and Technology Committee’s report on the UK’s battery strategy entitled “Battery strategy goes flat: Net-zero target at risk”. I currently co-chair the UK battery strategy task force, (https://www.gov.uk/government/news/government-holds-first-taskforce-for-the-uk-battery-strategy). I also disseminate my work via a start-up company Nyobolt that I helped to co-found and which specialises in fast-charging batteries (https://nyobolt.com/about-us/); the company has now grown to over 120 employees and has its first major customer. The company has used some of the metrology that we have developed as part of the BATNMR project. My groups activities are summarised on my group's website.

Fortschritte, die über den aktuellen Stand der Technik hinausgehen und voraussichtliche potenzielle Auswirkungen (einschließlich der bis dato erzielten sozioökonomischen Auswirkungen und weiter gefassten gesellschaftlichen Auswirkungen des Projekts)

We have developed a series of new characterisation methods that have moved magnetic resonance and optical spectroscopies beyond the state of the art. Via Overhauser dynamic nuclear polarisation methods we have enhanced the signals of Li metal dendrites by up to two orders of magnitude, developing a method that gives an unparalleled ability to see what is present at the interface between a Li metal dendrite and its passivation layers. Via optical and NMR methods was have developed new approaches to watch ions move in and out of particles and to monitor degradation of the liquids found in redox flow batteries.

Cartoon showing DNP and ESR studies of graphite

Optical vs SEM image - showing crack in niobium based anode material (crack seen in real time)