TeraHertz detection enabled by mOleculaR optomechanics

Project Information

THOR

Grant agreement ID: 829067

DOI

10.3030/829067

Project closed

EC signature date 16 January 2019

Start date 1 March 2019

End date 31 August 2022

Funded under

• EXCELLENT SCIENCE - Future and Emerging Technologies (FET)

Total cost

€ 3 274 122,50

EU contribution

€ 3 274 122,50

Coordinated by

UNIVERSITAT POLITECNICA DE VALENCIA
Spain

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Deliverables

Documents, reports (5)

Validation of experimental Raman spectra of the target molecules with strong Raman activity in the 1-30 THz region

Report on fabrication in integrated technology platform of dual THz-visible nanocavities with high g0/2π>10 GHz and C>1

Demonstration of hybrid nanocavities with Q > 1,000, and structured reservoir engineering

Report on the tradeoff between linewidth, confinement /optomechanical coupling strength, and geometry robustness

Molecular THz detector: Proof-of-concept

Open Research Data Pilot (1)

Data Management Plan

Websites, patent fillings, videos etc. (1)

Full website launch and final logo

Publications

Peer reviewed articles (35)

Integrated Sideband-Resolved SERS with a Dimer on a Nanobeam Hybrid

Author(s): Ilan Shlesinger, Isabelle M. Palstra, and A. Femius Koenderink
Published in: Phys. Rev. Lett., Issue Vol. 130, Issue 1, 2023, Page(s) 016901, ISSN 1079-7114
Publisher: American Physical Society
DOI: 10.1103/physrevlett.130.016901

Breaking the Selection Rules of Spin-Forbidden Molecular Absorption in Plasmonic Nanocavities

Author(s): Ojambati, Femi; Deacon, William M; Chikkaraddy, Rohit; Readman, Charlie; Lin, Qianqi; Koczor-Benda, Zsuzsanna; Rosta, Edina; Scherman, Oren; Baumberg, Jeremy
Published in: ACS Photonics, Issue 7, 2020, Page(s) 2337-2342, ISSN 2330-4022
Publisher: American Chemical Society
DOI: 10.17863/cam.56388

Dispersive optomechanics of supercavity modes in high-index disks

Author(s): Laura Mercadé, Ángela Barreda, Alejandro Martínez
Published in: Optics Letters, Issue 45/18, 2020, Page(s) 5238, ISSN 0146-9592
Publisher: Optical Society of America
DOI: 10.1364/ol.402398

SERS Detection via Individual Bowtie Nanoantennas Integrated in Si 3 N 4 Waveguides

Author(s): Amadeu Griol; Roel Baets; Alejandro Martínez; Javier Losada; Ali Raza; Aina Serrano; Stéphane Clemmen
Published in: IEEE journal of selected topics in quantum electronics, Issue Vol. 25. Nº 3, 2019, ISSN 1077-260X
Publisher: Institute of Electrical and Electronics Engineers
DOI: 10.1109/jstqe.2019.2896200

Molecular Screening for Terahertz Detection with Machine-Learning-Based Methods

Author(s): Zsuzsanna Koczor-Benda; Alexandra L. Boehmke; Angelos Xomalis; Rakesh Arul; Charlie Readman; Jeremy J. Baumberg; Edina Rosta
Published in: Physical Review X, Issue Vol. 11, Issue 4, 2021, Page(s) 041035, ISSN 2160-3308
Publisher: American Physical Society
DOI: 10.1103/physrevx.11.041035

Interfering Plasmons in Coupled Nanoresonators to Boost Light Localization and SERS

Author(s): Angelos Xomalis, Xuezhi Zheng, Angela Demetriadou, Alejandro Martínez, Rohit Chikkaraddy, Jeremy J. Baumberg
Published in: Nano Letters, Issue 21/6, 2021, Page(s) 2512-2518, ISSN 1530-6984
Publisher: American Chemical Society
DOI: 10.1021/acs.nanolett.0c04987

Optical probes of molecules as nano-mechanical switches.

Author(s): Dean Kos; Giuliana Di Martino; Alexandra Boehmke; Bart de Nijs; Dénes Berta; Tamás Földes; Sara Sangtarash; Edina Rosta; Hatef Sadeghi; Jeremy J. Baumberg
Published in: Nature Communications, Issue 11, 2020, Page(s) 5905 (2020), ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.17863/cam.59173

Quantum description of surface-enhanced resonant Raman scattering within a hybrid-optomechanical model

Author(s): Tomáš Neuman, Ruben Esteban, Geza Giedke, Mikołaj K. Schmidt, Javier Aizpurua
Published in: Physical Review A, Issue 100/4, 2019, Page(s) 043422, ISSN 2469-9926
Publisher: American Pysical Society
DOI: 10.1103/physreva.100.043422

Optomechanical Collective Effects in Surface-Enhanced Raman Scattering from Many Molecules

Author(s): Zhang, Yuan; Aizpurua, Javier; Esteban, Ruben
Published in: ACS Photonics, Issue 7-7, 2020, Page(s) 1676–1688, ISSN 2330-4022
Publisher: American Chemical Society
DOI: 10.1021/acsphotonics.0c00032

Single photon multiclock lock-in detection by picosecond time stamping

Author(s): Jeremy J. Baumberg; Lukas A. Jakob; William M. Deacon; Oliver Hicks; Ilya Manyakin; Oluwafemi Stephen Ojambati; Michael Traxler
Published in: Optica, Issue Vol. 8, issue 12, 2021, Page(s) 1646-1653, ISSN 2334-2536
Publisher: Optica Publishing Group
DOI: 10.1364/optica.441487

Addressing molecular optomechanical effects in nanocavity-enhanced Raman scattering beyond the single plasmonic mode

Author(s): Yuan Zhang, Ruben Esteban, Roberto A. Boto, Mattin Urbieta, Xabier Arrieta, ChongXin Shan, Shuzhou Li, Jeremy J. Baumberg, Javier Aizpurua
Published in: Nanoscale, Issue 13/3, 2021, Page(s) 1938-1954, ISSN 2040-3364
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0nr06649d

Integrated Molecular Optomechanics with Hybrid Dielectric–Metallic Resonators

Author(s): Ilan Shlesinger; Kévin G. Cognée; Ewold Verhagen; A. Femius Koenderink
Published in: ACS Photonics, Issue 8, 12, 2021, Page(s) 3506–3516, ISSN 2330-4022
Publisher: American Chemical Society
DOI: 10.1021/acsphotonics.1c00808

Collective Mid-Infrared Vibrations in Surface-Enhanced Raman Scattering.

Author(s): Niclas S. Mueller; Rakesh Arul; Lukas A. Jakob; Matthew Oliver Blunt; Tamás Földes; Edina Rosta; Jeremy J. Baumberg
Published in: Nano Letters, Issue 15306992, 2022, Page(s) 7254–7260, ISSN 1530-6992
Publisher: ACS Publications
DOI: 10.17863/cam.88941

Continuous-wave frequency upconversion with a molecular optomechanical nanocavity.

Author(s): Wen Chen; Philippe Roelli; Huatian Hu; Sachin Verlekar; Sakthi Priya Amirtharaj; Ángela I. Barreda; Tobias J. Kippenberg; Miroslavna Kovylina; Ewold Verhagen; Alejandro Martínez; Christophe Galland
Published in: Science, Issue VOL. 374, NO. 6572, 2021, Page(s) 1264-1267, ISSN 0036-8075
Publisher: American Association for the Advancement of Science
DOI: 10.1126/science.abk3106

Boosting Optical Nanocavity Coupling by Retardation Matching to Dark Modes

Author(s): Rohit Chikkaraddy, Junyang Huang, Dean Kos, Eoin Elliott, Marlous Kamp, Chenyang Guo, Jeremy J. Baumberg, and Bart de Nijs
Published in: ACS Photonics 2023, Issue 10 (2), 2023, Page(s) 493-499, ISSN 2330-4022
Publisher: American Chemical Society
DOI: 10.1021/acsphotonics.2c01603

Intrinsic luminescence blinking from plasmonic nanojunctions

Author(s): Wen Chen, Philippe Roelli, Aqeel Ahmed, Sachin Verlekar, Huatian Hu, Karla Banjac, Magalí Lingenfelder, Tobias J. Kippenberg, Giulia Tagliabue, Christophe Galland
Published in: Nature Communications, Issue 12/1, 2021, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-021-22679-y

Enhanced excitation and readout of plasmonic cavity modes in NPoM via SiN waveguides for on-chip SERS

Author(s): J. Enrique Vázquez-Lozano; Jeremy J. Baumberg; Alejandro Martínez
Published in: Optics Express, Issue Vol. 30, Issue 3, 2022, Page(s) 4553-4563, ISSN 1094-4087
Publisher: Optical Society of America
DOI: 10.1364/oe.446895

Tracking interfacial single-molecule pH and binding dynamics via vibrational spectroscopy.

Author(s): Junyang Huang; David-Benjamin Grys; Jack Griffiths; Bart de Nijs; Marlous Kamp; Qianqi Lin; Jeremy J. Baumberg
Published in: Science Advances, Issue Vol. 7, Issue 23, 2021, ISSN 2375-2548
Publisher: American Association for the Advancement of Science
DOI: 10.1126/sciadv.abg1790

Accessing Plasmonic Hotspots Using Nanoparticle-on-Foil Constructs

Author(s): Rohit Chikkaraddy, Jeremy J Baumberg
Published in: ACS Photonics, 2021, ISSN 2330-4022
Publisher: American Chemical Society
DOI: 10.1021/acsphotonics.1c01048

Giant mid-IR resonant coupling to molecular vibrations in sub-nm gaps of plasmonic multilayer metafilms

Author(s): Arul, R., Grys, DB., Chikkaraddy, R. et al.
Published in: Light Sci Appl, Issue 11, 2022, Page(s) 281, ISSN 2047-7538
Publisher: Springer Nature
DOI: 10.1038/s41377-022-00943-0

Molecular Optomechanics Approach to Surface-Enhanced Raman Scattering

Author(s): Rubén Esteban, Jeremy J. Baumberg, Javier Aizpurúa
Published in: Acc. Chem. Res, Issue 55, 2022, Page(s) 1889-1899, ISSN 0001-4842
Publisher: American Chemical Society
DOI: 10.1021/acs.accounts.1c00759

Accurate Transfer of Individual Nanoparticles onto Single Photonic Nanostructures

Author(s): Javier Redolat, María Camarena-Pérez, Amadeu Griol, Miroslavna Kovylina, Angelos Xomalis, Jeremy J. Baumberg, Alejandro Martínez, and Elena Pinilla-Cienfuegos
Published in: ACS Applied Materials & Interfaces, Issue 15 (2), 2023, Page(s) 3558-3565, ISSN 2330-4022
Publisher: American Chemical Society
DOI: 10.1021/acsami.2c13633

Mid-infrared-perturbed molecular vibrational signatures in plasmonic nanocavities.

Author(s): Chikkaraddy, Rohit; Xomalis, Angelos; Jakob, Lukas A.; Baumberg, Jeremy J.
Published in: Light: Science & Applications volume, Issue 11, Article number: 19, 2022, ISSN 2047-7538
Publisher: Springer Nature
DOI: 10.1038/s41377-022-00709-8

Detecting mid-infrared light by molecular frequency upconversion in dual-wavelength nanoantennas

Author(s): Angelos Xomalis; Xuezhi Zheng; Xuezhi Zheng; Rohit Chikkaraddy; Zsuzsanna Koczor-Benda; Ermanno Miele; Edina Rosta; Guy A. E. Vandenbosch; Alejandro Martínez; Jeremy J. Baumberg
Published in: Science, Issue Vol 374, Issue 6572, 2021, Page(s) 1268-1271, ISSN 0036-8075
Publisher: American Association for the Advancement of Science
DOI: 10.1126/science.abk2593

Energy-resolved plasmonic chemistry in individual nanoreactors

Author(s): Eitan Oksenberg , Ilan Shlesinger, Angelos Xomalis, Andrea Baldi, Jeremy J. Baumberg, A. Femius Koenderink  and Erik C. Garnett
Published in: Nature Nanotechnology, Issue 16, 2021, Page(s) 1378–1385, ISSN 1748-3395
Publisher: Springer Nature
DOI: 10.1038/s41565-021-00973-6

Quantum theory of surface-enhanced resonant Raman scattering (SERRS) of molecules in strongly coupled plasmon–exciton systems

Author(s): Tomáš Neuman, Javier Aizpurua, Ruben Esteban
Published in: Nanophotonics, Issue 9/2, 2020, Page(s) 295-308, ISSN 2192-8614
Publisher: De Gruyter
DOI: 10.1515/nanoph-2019-0336

Frequency-resolved photon correlations in cavity optomechanics

Author(s): M K Schmidt, R Esteban, G Giedke, J Aizpurua, A González-Tudela
Published in: Quantum Science and Technology, Issue 6/3, 2021, Page(s) 034005, ISSN 2058-9565
Publisher: IOPScience
DOI: 10.1088/2058-9565/abe569

Molecular Platform for Frequency Upconversion at the Single-Photon Level

Author(s): Philippe Roelli, Diego Martin-Cano, Tobias J. Kippenberg, Christophe Galland
Published in: Physical Review X, Issue 10/3, 2020, ISSN 2160-3308
Publisher: American Physical Society
DOI: 10.1103/physrevx.10.031057

Vibrational Stark Effects: Ionic Influence on Local Fields

Author(s): Wright, Demelza; Sangtarash, Sara; Mueller, Niclas S; Lin, Qianqi; Sadeghi, Hatef; Baumberg, Jeremy
Published in: The Journal of Physical Chemistry Letters, Issue 13, 2022, Page(s) 4905-4911, ISSN 1948-7185
Publisher: American Chemical Society
DOI: 10.1021/acs.jpclett.2c01048

Molecular Vibration Explorer: an Online Database and Toolbox for Surface-Enhanced Frequency Conversion and Infrared and Raman Spectroscopy

Author(s): Zsuzsanna Koczor-Benda, Philippe Roelli, Christophe Galland, and Edina Rosta
Published in: The Journal of Physical Chemistry A, Issue 126 (28), 2022, Page(s) 4657–4663, ISSN 1932-7455
Publisher: ACS Publications
DOI: 10.1021/acs.jpca.2c03700

Collective Mid-Infrared Vibrations in Surface-Enhanced Raman Scattering

Author(s): Niclas S. Mueller, Rakesh Arul, Lukas A. Jakob, Matthew Oliver Blunt, Tamás Földes, Edina Rosta, and Jeremy J. Baumberg
Published in: Nano Letters, Issue 22 (17), 2022, Page(s) 7254-7260, ISSN 1530-6992
Publisher: American Chemical Society
DOI: 10.1021/acs.nanolett.2c02806

Multi-wavelength lock-in spectroscopy for extracting perturbed spectral responses: molecular signatures in nanocavities

Author(s): Angelos Xomalis and Jeremy J. Baumberg
Published in: Optics Express, Issue Vol. 31, Issue 3, 2023, Page(s) 5069-5074, ISSN 1094-4087
Publisher: Optical Society of America
DOI: 10.1364/oe.481639

Controlling Optically Driven Atomic Migration Using Crystal-Facet Control in Plasmonic Nanocavities

Author(s): Angelos Xomalis, Rohit Chikkaraddy, Eitan Oksenberg, Ilan Shlesinger, Junyang Huang, Erik C. Garnett, A. Femius Koenderink, Jeremy J. Baumberg
Published in: ACS Nano, Issue 14/8, 2020, Page(s) 10562-10568, ISSN 1936-0851
Publisher: American Chemical Society
DOI: 10.1021/acsnano.0c04600

Hybrid photonic-plasmonic cavities based on the nanoparticle-on-a-mirror configuration

Author(s): Ángela I. Barreda; Mario Zapata-Herrera; Isabelle M. Palstra; Laura Mercadé; Javier Aizpurua; A. Femius Koenderink; Alejandro Martínez
Published in: Photonics Research, Issue Vol.9, Issue 12, 2021, Page(s) 2398-2419, ISSN 2327-9125
Publisher: Optica Publishing Group
DOI: 10.1364/prj.433761

Hybrid Photonic-Plasmonic Cavity Design for Very Large Purcell Factors at Telecommunication Wavelengths

Author(s): Angela Barreda; Laura Mercadé; Mario Zapata-Herrera; Javier Aizpurua; Alejandro Martínez
Published in: PHYSICAL REVIEW APPLIED, Issue 18, 2022, Page(s) 044066, ISSN 2331-7019
Publisher: American Physical Society
DOI: 10.1103/physrevapplied.18.044066