Chirality and spin selectivity in electron transfer processes: from quantum detection to quantum enabled technologies

Informacje na temat projektu

CASTLE

Identyfikator umowy o grant: 101071533

DOI

10.3030/101071533

Data podpisania przez KE 22 Listopada 2022

Data rozpoczęcia 1 Stycznia 2023

Data zakończenia 31 Grudnia 2028

Finansowanie w ramach

• European Research Council (ERC)

Koszt całkowity

€ 8 976 957,00

Wkład UE

€ 8 976 957,00

Koordynowany przez

UNIVERSITA DEGLI STUDI DI FIRENZE
Italy

CORDIS oferuje możliwość skorzystania z odnośników do publicznie dostępnych publikacji i rezultatów projektów realizowanych w ramach programów ramowych HORYZONT.

Odnośniki do rezultatów i publikacji związanych z poszczególnymi projektami 7PR, a także odnośniki do niektórych konkretnych kategorii wyników, takich jak zbiory danych i oprogramowanie, są dynamicznie pobierane z systemu OpenAIRE .

Publikacje

Peer reviewed articles (32)

Chirality Versus Symmetry: Electron's Spin Selectivity in Nonpolar Chiral Lead–Bromide Perovskites

Autorzy: A. Abhervé, N. Mercier, A. Kumar, T. K. Das, J. Even, C. Katan and M. Kepenekian
Opublikowane w: Advanced Materials, 2023, ISSN 0935-9648
Wydawca: John Wiley & Sons, Ltd
DOI: 10.1002/adma.202305784

Journal of the American Chemical Society

Autorzy: H. J. Eckvahl, G. Copley, R. M. Young, M. D. Krzyaniak and M. R. Wasielewski
Opublikowane w: Journal of the American Chemical Society, 2024, ISSN 0002-7863
Wydawca: American Chemical Society
DOI: 10.1021/jacs.4c08706

Metalloporphyrins as Building Blocks for Quantum Information Science

Autorzy: Fabio Santanni; Alberto Privitera
Opublikowane w: Advanced Optical Materials, 2024, ISSN 2195-1071
Wydawca: Wiley
DOI: 10.1002/adom.202303036

Spin polarized current in chiral organic radical monolayers

Autorzy: Giaconi, Niccolò; Lupi, Michela; Das, Tapan Kumar; Kumar, Anil; Poggini, Lorenzo; Viglianisi, Caterina; Sorace, Lorenzo; Menichetti, Stefano; Naaman, Ron; Sessoli, Roberta; Mannini, Matteo
Opublikowane w: Journal of Material Chemistry C, Numer 12, 2024, ISSN 2050-7526
Wydawca: Royal Society of Chemistry , UK
DOI: 10.1039/D4TC00944D

Ab initio parametrization of a generalized Hubbard model in a molecule displaying chirality-induced spin selectivity

Autorzy: D. K. Andrea Phan Huu, Arianna Cantarella, Pietro Bonfà, Lorenzo Savi, Alessandro Chiesa, Anna Painelli, Stefano Carretta
Opublikowane w: Communications Materials, Numer 6, 2025, ISSN 2662-4443
Wydawca: Springer Science and Business Media LLC
DOI: 10.1038/S43246-025-00821-3

Chirality-Induced Spin Selectivity: A Minimal Model

Autorzy: Lorenzo Savi, Leonardo Celada, D.K. Andrea Phan Huu, Alessandro Chiesa, Stefano Carretta, Anna Painelli
Opublikowane w: The Journal of Physical Chemistry Letters, Numer 16, 2025, ISSN 1948-7185
Wydawca: American Chemical Society (ACS)
DOI: 10.1021/ACS.JPCLETT.5C01813

Dual structure of a vanadyl-based molecular qubit containing a bis(beta-diketonato) ligand

Autorzy: Manuel Imperato, Alessio Nicolini, Matteo Boniburini, Daniele Sartini, Enrico Benassi, Mario Chiesa, Lara Gigli, Yu-Kai Liao, Arsen Raza, Enrico Salvadori, Lorenzo Sorace, Andrea Cornia
Opublikowane w: Inorganic Chemistry, 2024, ISSN 0020-1669
Wydawca: American Chemical Society
DOI: 10.5281/zenodo.13362609

Detecting Chirality-Induced Spin Selectivity in Randomly Oriented Radical Pairs Photogenerated by Hole Transfer

Autorzy: Hannah J. Eckvahl, Graeme Copley, Ryan M. Young, Matthew D. Krzyaniak, Michael R. Wasielewski
Opublikowane w: Journal of the American Chemical Society, Numer 146, 2024, ISSN 0002-7863
Wydawca: American Chemical Society (ACS)
DOI: 10.1021/JACS.4C08706

Light-Activated Qubit Coupling in a Vanadyl Porphyrin Trimer

Autorzy: Alberto Privitera, Alessandro Chiesa, Fabio Santanni, Davide Ranieri, Prem P. Sahu, Matthew D. Krzyaniak, Andrea Caneschi, Ryan M. Young, Mathias O. Senge, Federico Totti, Michael R. Wasielewski, Stefano Carretta, Roberta Sessoli
Opublikowane w: Journal of the American Chemical Society, Numer 148, 2026, ISSN 0002-7863
Wydawca: American Chemical Society (ACS)
DOI: 10.1021/JACS.5C17205

Chirality-Induced Spin Selectivity at the Molecular Level: A Different Perspective to Understand and Exploit the Phenomenon

Autorzy: Alessandro Chiesa, Alberto Privitera, Elena Garlatti, Giuseppe Allodi, Robert Bittl, Michael R. Wasielewski, Roberta Sessoli, Stefano Carretta
Opublikowane w: The Journal of Physical Chemistry Letters, Numer 16, 2025, ISSN 1948-7185
Wydawca: American Chemical Society (ACS)
DOI: 10.1021/ACS.JPCLETT.5C00755

Chiral-induced spin selectivity in photo-induced electron transfer: Investigating charge and spin dynamics in a master equation framework

Autorzy: Emilio Macaluso; Alessandro Chiesa; Paolo Santini; Robert Bittl; Stefano Carretta
Opublikowane w: The Journal of Chemical Physics, 2023, ISSN 1089-7690
Wydawca: American Institute of Physics
DOI: 10.17169/refubium-40304

Conclusive Insight into the Coordination Complexes of a Flexible Bis(β‐diketonato) Ligand and Their Phase‐Dependent Structure: A Multi‐Technique Approach

Autorzy: Manuel Imperato; Alessio Nicolini; Olga Mironova; Enrico Benassi; Nicola Demitri; Lara Gigli; Adele Mucci; Andrea Cornia
Opublikowane w: Chemistry – A European Journal, 2025, ISSN 1521-3765
Wydawca: Wiley, Wiley-VCH
DOI: 10.1002/CHEM.202500697

Oxovanadium(IV) Thiocarboxylate Paddlewheels Containing Ancillary Group 10 Metals: A Comparative Study on Pd and Pt Derivatives

Autorzy: Olga Mironova, Giacomo Bellini, Alessio Nicolini, Manuel Imperato, Antonio Ranieri, Marco Borsari, Matteo Briganti, Rodolphe Clérac, Mathieu Rouzières, Enrico Salvadori, Maria Chiara Pagliero, Mario Chiesa, Andrea Cornia
Opublikowane w: Inorganic Chemistry, Numer 65, 2025, ISSN 0020-1669
Wydawca: American Chemical Society (ACS)
DOI: 10.5281/ZENODO.17865582

Room-Temperature Optical Spin Polarization of an Electron Spin Qudit in a Vanadyl-Free Base Porphyrin Dimer

Autorzy: Alberto Privitera, Alessandro Chiesa, Fabio Santanni, Angelo Carella, Davide Ranieri, Andrea Caneschi, Matthew D. Krzyaniak, Ryan M. Young, Michael R. Wasielewski, Stefano Carretta, Roberta Sessoli
Opublikowane w: Journal of the American Chemical Society, Numer 147, 2025, ISSN 0002-7863
Wydawca: American Chemical Society (ACS)
DOI: 10.1021/JACS.4C10632

Molecular nanomagnets: a viable path toward quantum information processing?

Autorzy: A. Chiesa, P. Santini, E. Garlatti, F. Luis, S. Carretta
Opublikowane w: Reports on Progress in Physics, 2024, ISSN 1361-6633
Wydawca: IOP Publishing
DOI: 10.1088/1361-6633/ad1f81

A Lewis Base Hydrogen Bond Donor (LB/HBD) Organocatalytic Approach to Dithiabridged Triarylamine Hetero[4]helicenes

Autorzy: M. Lupi, O. Salmi, C. Viglianisi and S. Menichetti
Opublikowane w: Advanced Synthesis & Catalysis, 2023, ISSN 1615-4150
Wydawca: John Wiley & Sons Ltd.
DOI: 10.1002/adsc.202300238

Chirality‐Induced Spin Selectivity: An Enabling Technology for Quantum Applications

Autorzy: Chiesa, Alessandro; Privitera, Alberto; Macaluso, Emilio; Mannini, Matteo; Bittl, Robert; Naaman, Ron; Wasielewski, Michael R.; Sessoli, Roberta; Carretta, Stefano
Opublikowane w: Advanced Materials, 2023, ISSN 1521-4095
Wydawca: Wiley, Wiley-VCH
DOI: 10.17169/refubium-40306

Many-Body Models for Chirality-Induced Spin Selectivity in Electron Transfer

Autorzy: A. Chiesa, E. Garlatti, M. Mezzadri, L. Celada, R. Sessoli, M. R. Wasielewski, R. Bittl, P. Santini, S. Carretta
Opublikowane w: Nano Letters, 2024, ISSN 1530-6984
Wydawca: American Chemical Society
DOI: 10.48550/arXiv.2406.15135

Spin-selective charge transfer pathways in photoexcited helicene-perylenediimide dyads

Autorzy: Giulia Agnoloni, Angelo Carella, Jakob K. Staab, Maksim Arsentev, Michela Lupi, Stefano Menichetti, Caterina Viglianisi, Ryan M. Young, Federico Totti, Michael R. Wasielewski, Alberto Privitera, Roberta Sessoli
Opublikowane w: Journal of Materials Chemistry C, Numer 14, 2026, ISSN 2050-7526
Wydawca: Royal Society of Chemistry (RSC)
DOI: 10.1039/D6TC01492E

The Role of Chirality-Induced Spin Selectivity in Helicene-Based Photogenerated Radical Pairs

Autorzy: Giulia Agnoloni, Alessandro Chiesa, Ryan M. Young, Federico Totti, Stefano Menichetti, Caterina Viglianisi, Michael R. Wasielewski, Stefano Carretta, Alberto Privitera, Roberta Sessoli
Opublikowane w: Journal of the American Chemical Society, Numer 148, 2026, ISSN 0002-7863
Wydawca: American Chemical Society (ACS)
DOI: 10.1021/JACS.6C02634

Journal of the American Chemical Society

Autorzy: Alberto Privitera; Alessandro Chiesa; Fabio Santanni; Angelo Carella; Davide Ranieri; Andrea Caneschi; Matthew D. Krzyaniak; Ryan M. Young; Michael R. Wasielewski; Stefano Carretta; Roberta Sessoli
Opublikowane w: Journal of the American Chemical Society, 2025, ISSN 0002-7863
Wydawca: American Chemical Society
DOI: 10.1021/JACS.4C10632

Vibrationally Mediated Dzyaloshinskii-Moriya Interactionas the Origin of Chirality-Induced Spin Selectivity in Donor–AcceptorMolecules

Autorzy: Alessandro Chiesa, D. K. Andrea Phan Huu, Arianna Cantarella, Leonardo Celada, Michael R. Wasielewski, Paolo Santini, Stefano Carretta
Opublikowane w: Nano Letters, Numer 26, 2026, ISSN 1530-6984
Wydawca: American Chemical Society (ACS)
DOI: 10.1021/ACS.NANOLETT.6C01653

Efficient Spin-Selective Electron Transport at Low Voltages of Thia-Bridged Triarylamine Hetero[4]helicenes Chemisorbed Monolayer

Autorzy: N. Giaconi, L. Poggini, M. Lupi, M. Briganti, A. Kumar, T. K. Das, A. L. Sorrentino, C. Viglianisi, S. Menichetti, R. Naaman, R. Sessoli and M. Mannini
Opublikowane w: ACS Nano, 2023, ISSN 1936-0851
Wydawca: American Chemical Society
DOI: 10.1021/acsnano.3c04878

Direct observation of chirality-induced spin selectivity in electron donor–acceptor molecules

Autorzy: Hannah J. Eckvahl; Nikolai A. Tcyrulnikov; Alessandro Chiesa; Jillian M. Bradley; Ryan M. Young; Stefano Carretta; Matthew D. Krzyaniak; Michael R. Wasielewski
Opublikowane w: Science, 2023, ISSN 1095-9203
Wydawca: merican Association for the Advancement of Science
DOI: 10.48550/arxiv.2311.03599

Multiple Dimerization Modes in Thiocarboxylate Paddlewheel Complexes: A Comprehensive View of Energy Landscapes from DFT Calculations and Statistics

Autorzy: Olga Mironova, Giacomo Bellini, Alessio Nicolini, Andrea Cornia
Opublikowane w: Chemistry – A European Journal, 2025, ISSN 0947-6539
Wydawca: Wiley
DOI: 10.5281/ZENODO.17793316

Circularly Polarized Luminescence and Photoinduced Spin Polarization in Helicene-Bis-TEMPO Diradicals

Autorzy: Stefano Cadeddu, Rituparno Chowdhury, Chiara Delpiano Cordeiro, Saurav Parmar, Augusta Kramer, Marie Cordier, Anne Pensel, Nicolas Vanthuyne, Roberta Sessoli, Mario Chiesa, Yu-Kai Liao, Richard H. Friend, Enrico Salvadori, Jochen Autschbach, Jeanne Crassous
Opublikowane w: Journal of the American Chemical Society, Numer 147, 2025, ISSN 0002-7863
Wydawca: American Chemical Society (ACS)
DOI: 10.1021/JACS.5C04887

Organic and Biomolecular Chemistry

Autorzy: M. Lupi, M. Fabbri, G. Mazzeo, G. Longhi, S. Abbate, C. Viglianisi and S. Menichetti
Opublikowane w: Organic & Biomolecular Chemistry, 2024, ISSN 1477-0520
Wydawca: Royal Society of Chemistry
DOI: 10.1039/D4OB00979G

Detecting chirality-induced spin selectivity in chromophore-linked DNA hairpins using photogenerated radical pairs

Autorzy: Elisabeth I. Latawiec, Alessandro Chiesa, Yunfan Qiu, Nikolai A. Tcyrulnikov, Ryan M. Young, Stefano Carretta, Matthew D. Krzyaniak, Michael R. Wasielewski
Opublikowane w: Proceedings of the National Academy of Sciences, Numer 122, 2025, ISSN 0027-8424
Wydawca: Proceedings of the National Academy of Sciences
DOI: 10.1073/PNAS.2515120122

Quantum spin coherence and electron spin distribution channels in vanadyl-containing lantern complexes

Autorzy: Manuel Imperato, Alessio Nicolini, Marco Borsari, Matteo Briganti, Mario Chiesa, Yu-Kai Liao, Antonio Ranieri, Arsen Raza, Enrico Salvadori, Lorenzo Sorace, Andrea Cornia
Opublikowane w: Inorganic Chemistry Frontiers, 2023, ISSN 2052-1545
Wydawca: Royal Sociaty of Chemistry
DOI: 10.1039/d3qi01806g

Efficient Chirality-Induced Spin Selectivity in Self-Assembled Monolayers of Ru ₂ ⁵ ⁺ Paddlewheel Complexes

Autorzy: Isabel Coloma, Niccolò Giaconi, Francesco Parmeggiani, Thierry Buffeteau, Gilles Pécastaings, Santiago Herrero, Elizabeth A. Hillard, Patrick Rosa, Lorenzo Poggini, Matteo Mannini, Miguel Cortijo, Mathieu Gonidec
Opublikowane w: Journal of the American Chemical Society, Numer 148, 2026, ISSN 0002-7863
Wydawca: American Chemical Society (ACS)
DOI: 10.1021/JACS.6C02811

Challenges in the Direct Detection of Chirality‐induced Spin Selectivity: Investigation of Foldamer‐based Donor‐acceptor Dyads

Autorzy: Privitera, Alberto; Faccio, Davide; Giuri, Demetra; Latawiec, Elisabeth I.; Genovese, Damiano; Tassinari, Francesco; Mummolo, Liviana; Chiesa, Mario; FONTANESI, Claudio; Salvadori, Enrico; Cornia, Andrea; Wasielewski, Michael; Claudia, Tomasini; Sessoli, Roberta
Opublikowane w: Chemistry- A European Journal, 2023, ISSN 1521-3765
Wydawca: Wiley, Wiley-VCH
DOI: 10.1002/chem.202301005

Weak Exchange Interactions in Multispin Systems: EPR Studies of Metalloporphyrins Decorated with {Cr7Ni} Rings

Autorzy: F. Santanni, E. Little, S. J. Lockyer, G. F. S. Whitehead, E. J. L. McInnes, G. A. Timco, A. M. Bowen, R. Sessoli and R. E. P. Winpenny
Opublikowane w: Inorganic Chemistry, 2024, ISSN 0020-1669
Wydawca: American Chemical Society
DOI: 10.1021/acs.inorgchem.4c01248